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2011


Quantum-Cascade Laser-Based Vibrational Circular Dichroism
Quantum-Cascade Laser-Based Vibrational Circular Dichroism

Luedeke, S., Pfeifer, M., Fischer, P.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 133(15):5704-5707, 2011 (article)

Abstract
Vibrational circular dichroism (VCD) spectra were recorded with a tunable external-cavity quantum-cascade laser (QCL). In comparison with standard thermal light sources in the IR, QCLs provide orders of magnitude more power and are therefore promising for VCD studies in strongly absorbing solvents. The brightness of this novel light source is demonstrated with VCD and IR absorption measurements of a number of compounds, including proline in water.

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DOI [BibTex]

2011


DOI [BibTex]


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Collective dynamics of colloids at fluid interfaces

Bleibel, J., Dominguez, A., Oettel, M., Dietrich, S.

European Physical Journal E, 34(11), 2011 (article)

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DOI [BibTex]

DOI [BibTex]


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Anomalous transport of a tracer on percolating clusters

Spanner, M., Höfling, F., Schröder-Turk, G. E., Mecke, K., Franosch, T.

Journal of Physics: Condensed Matter, 23(23), 2011 (article)

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DOI [BibTex]

DOI [BibTex]


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Dynamics of colloids in confined geometries

Almenar, L., Rauscher, M.

Journal of Physics: Condensed Matter, 23(18), 2011 (article)

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link (url) DOI [BibTex]

link (url) DOI [BibTex]


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The structure and melting transition of two-dimensional colloidal alloys

Law, A. D., Horozov, T. S., Buzza, D. M. A.

Soft Matter, 7(19):8923-8931, 2011 (article)

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DOI [BibTex]

DOI [BibTex]


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Second harmonic light scattering from spherical polyelectrolyte brushes

Schürer, B., Hoffmann, M., Wunderlich, S., Harnau, L., Peschel, U., Ballauff, M., Peukert, W.

Journal of Physical Chemistry C, 115, pages: 18302-18309, 2011 (article)

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DOI [BibTex]

DOI [BibTex]


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Simulation einer fast kritischen binären Flüssigkeit in einem Temperaturgradienten

Single, F.

Universität Stuttgart, Stuttgart, 2011 (mastersthesis)

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[BibTex]

[BibTex]


Actively coupled cavity ringdown spectroscopy with low-power broadband sources
Actively coupled cavity ringdown spectroscopy with low-power broadband sources

Petermann, C., Fischer, P.

OPTICS EXPRESS, 19(11):10164-10173, 2011 (article)

Abstract
We demonstrate a coupling scheme for cavity enhanced absorption spectroscopy that makes use of an intracavity acousto-optical modulator to actively switch light into (and out of) a resonator. This allows cavity ringdown spectroscopy (CRDS) to be implemented with broadband nonlaser light sources with spectral power densities of less than 30 mu W/nm. Although the acousto-optical element reduces the ultimate detection limit by introducing additional losses, it permits absorptivities to be measured with a high dynamic range, especially in lossy environments. Absorption measurements for the forbidden transition of gaseous oxygen in air at similar to 760nm are presented using a low-coherence cw-superluminescent diode. The same setup was electronically configured to cover absorption losses from 1.8 x 10(-8)cm(-1) to 7.5\% per roundtrip. This could be of interest in process analytical applications. (C) 2011 Optical Society of America

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DOI [BibTex]

DOI [BibTex]


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Solvation forces in Ising films with long-range boundary fields: density-matrix renormalization-group study

Drzewinski, A., Maciolek, A., Barasinski, A.

Molecular Physics, 109(7-10):1133-1141, 2011 (article)

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DOI [BibTex]

DOI [BibTex]


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Pulling and pushing a cargo with a catalytically active carrier

Popescu, M. N., Tasinkevych, M., Dietrich, S.

Europhysics Letters, 95(2), 2011 (article)

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DOI [BibTex]

DOI [BibTex]


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Critical Casimir forces for Ising films with variable boundary fields

Vasilyev, O., Maciolek, A., Dietrich, S.

Physical Review E, 84(4), 2011 (article)

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DOI [BibTex]


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Study of \pi\pi correlations at LHC and RHIC energies in pp collisions within the quark-gluon string model

Nilsson, M. S., Bravina, L. V., Zabrodin, E. E., Malinina, L. V., Bleibel, J.

Physical Review D, 84(5), 2011 (article)

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DOI [BibTex]

DOI [BibTex]


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Micro-rheology on (polymer-grafted) colloids using optical tweezers

Gutsche, C., Elmahdy, M. M., Kegler, K., Semenov, I., Stangner, T., Otto, O., Ueberschär, O., Keyser, U. F., Krüger, M., Rauscher, M., Weeber, R., Harting, J., Kim, Y. W., Lobaskin, V., Netz, R., Kremer, F.

Journal of Physics: Condensed Matter, 23(18), IOP Publishing, Bristol, 2011 (article)

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DOI [BibTex]

DOI [BibTex]


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Debye-Scherrer rings from block copolymer films with powder-like order

Busch, P., Rauscher, M., Moulin, J.-F., Müller-Buschbaum, P.

Journal of Applied Crystallography, 44(2):370-379, 2011 (article)

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DOI [BibTex]

DOI [BibTex]


Magnetically actuated propulsion at low Reynolds numbers: towards nanoscale control
Magnetically actuated propulsion at low Reynolds numbers: towards nanoscale control

Fischer, P., Ghosh, A.

NANOSCALE, 3(2):557-563, 2011 (article)

Abstract
Significant progress has been made in the fabrication of micron and sub-micron structures whose motion can be controlled in liquids under ambient conditions. The aim of many of these engineering endeavors is to be able to build and propel an artificial micro-structure that rivals the versatility of biological swimmers of similar size, e. g. motile bacterial cells. Applications for such artificial ``micro-bots'' are envisioned to range from microrheology to targeted drug delivery and microsurgery, and require full motion-control under ambient conditions. In this Mini-Review we discuss the construction, actuation, and operation of several devices that have recently been reported, especially systems that can be controlled by and propelled with homogenous magnetic fields. We describe the fabrication and associated experimental challenges and discuss potential applications.

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Video - Nanospropellers DOI [BibTex]


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Effective interactions and equilibrium configurations of colloidal particles on a sessile droplet

Guzowski, J., Tasinkevych, M., Dietrich, S.

Soft Matter, 7(9):4189-4197, 2011 (article)

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DOI [BibTex]

DOI [BibTex]


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Capillary interactions in Pickering emulsions

Guzowski, J., Tasinkevych, M., Dietrich, S.

Physical Review E, 84(3), 2011 (article)

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DOI [BibTex]

DOI [BibTex]


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Critical Casimir forces steered by patterned substrates

Gambassi, A., Dietrich, S.

Soft Matter, 7(4):1247-1253, 2011 (article)

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DOI [BibTex]

DOI [BibTex]


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Interaction strength between proteins and polyelectrolyte brushes: A small angle X-ray scattering study

Henzler, K., Haupt, B., Rosenfeldt, S., Harnau, L., Narayanan, T., Ballauff, M.

Physical Chemistry Chemical Physics, 13, pages: 17599-17605, 2011 (article)

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DOI [BibTex]

DOI [BibTex]


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Annealing of single lamella nanoparticles of polyethylene

Rochette, C. N., Rosenfeldt, S., Henzler, K., Polzer, F., Ballauff, M., Tong, Q., Mecking, S., Drechsler, M., Narayanan, T., Harnau, L.

Macromolecules, 44(12):4845-4851, 2011 (article)

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DOI [BibTex]

DOI [BibTex]


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Struktur dichter ionischer Flüssigkeiten

Dannenmann, O.

Universität Stuttgart, Stuttgart, 2011 (mastersthesis)

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[BibTex]

[BibTex]


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Trapping colloids near chemical stripes via critical Casimir forces

Tröndle, M., Zvyagolskaya, O., Gambassi, A., Vogt, D., Harnau, L., Bechinger, C., Dietrich, S.

Molecular Physics, 109, pages: 1169-1185, 2011 (article)

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DOI [BibTex]

DOI [BibTex]


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Electrostatic interactions in critical solvents

Bier, M., Gambassi, A., Oettel, M., Dietrich, S.

Europhysics Letters, 95, 2011 (article)

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DOI [BibTex]

DOI [BibTex]


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Structural investigation of thin diblock copolymer films using time-of-flight grazing-incidence small-angle neutron scattering

Metwalli, E., Moulin, J.-F., Rauscher, M., Kaune, G., Ruderer, M. A., Van Bürck, U., Haese-Seiller, M., Kampmann, R., Müller-Buschbaum, P.

Journal of Applied Crystallography, 44(1):84-92, 2011 (article)

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DOI [BibTex]

DOI [BibTex]


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Complexation of beta-lactoglobulin fibrils and sulfated polysaccharides

Jones, O. G., Handschin, S., Adamcik, J., Harnau, L., Bolisetty, S., Mezzenga, R.

Biomacromolecules, 12, pages: 3056-3065, 2011 (article)

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DOI [BibTex]

DOI [BibTex]


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Parallelisierung Stokesscher Dynamik für Graphikprozessoren zur Simulation kolloidaler Suspensionen

Kopp, M.

Universität Stuttgart, Stuttgart, 2011 (mastersthesis)

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[BibTex]

[BibTex]


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Diffusion in Wandnähe

Müller, J.

Universität Stuttgart, Stuttgart, 2011 (mastersthesis)

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[BibTex]

[BibTex]


Weak value amplified optical activity measurements
Weak value amplified optical activity measurements

Pfeifer, M., Fischer, P.

Opt. Express, 19(17):16508-16517, OSA, 2011 (article)

Abstract
We present a new form of optical activity measurement based on a modified weak value amplification scheme. It has recently been shown experimentally that the left- and right-circular polarization components refract with slightly different angles of refraction at a chiral interface causing a linearly polarized light beam to split into two. By introducing a polarization modulation that does not give rise to a change in the optical rotation it is possible to differentiate between the two circular polarization components even after post-selection with a linear polarizer. We show that such a modified weak value amplification measurement permits the sign of the splitting and thus the handedness of the optically active medium to be determined. Angular beam separations of Δθ ∼ 1 nanoradian, which corresponds to a circular birefringence of Δn ∼ 1 × 10−9, could be measured with a relative error of less than 1%.

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link (url) DOI [BibTex]

link (url) DOI [BibTex]


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Magnetization of multicomponent ferrofluids

Szalai, I., Dietrich, S.

Journal of Physics: Condensed Matter, 23(32), 2011 (article)

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DOI [BibTex]

DOI [BibTex]


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Space-resolved dynamics of a tracer in a disordered solid

Franosch, T., Spanner, M., Bauer, T., Schröder-Turk, G. E., Höfling, F.

Journal of Non-Crystalline Solids, 357(2):472-478, 2011 (article)

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DOI [BibTex]

DOI [BibTex]


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Long-wavelength anomalies in the asymptotic behavior of mode-coupling theory

Schnyder, S. K., Höfling, F., Franosch, T., Voigtmann, T.

Journal of Physics: Condensed Matter, 23(23), 2011 (article)

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DOI [BibTex]

DOI [BibTex]


Nonlinear optical spectroscopy of chiral molecules
Nonlinear optical spectroscopy of chiral molecules

Fischer, P., Hache, F.

CHIRALITY, 17(8):421-437, 2005 (article)

Abstract
We review nonlinear optical processes that are specific to chiral molecules in solution and on surfaces. In contrast to conventional natural optical activity phenomena, which depend linearly on the electric field strength of the optical field, we discuss how optical processes that are nonlinear (quadratic, cubic, and quartic) functions of the electromagnetic field strength may probe optically active centers and chiral vibrations. We show that nonlinear techniques open entirely new ways of exploring chirality in chemical and biological systems: The cubic processes give rise to nonlinear circular dichroism and nonlinear optical rotation and make it possible to observe dynamic chiral processes at ultrafast time scales. The quadratic second-harmonic and sum-frequency-generation phenomena and the quartic processes may arise entirely in the electric-dipole approximation and do not require the use of circularly polarized light to detect chirality: They provide surface selectivity and their observables can be relatively much larger than in linear optical activity. These processes also give rise to the generation of light at a new color, and in liquids this frequency conversion only occurs if the solution is optically active. We survey recent chiral nonlinear optical experiments and give examples of their application to problems of biophysical interest. (C) 2005 Wiley-Liss, Inc.

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DOI [BibTex]

DOI [BibTex]


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Global phase diagrams of binary dipolar fluid mixtures

Szalai, I., Dietrich, S.

Molecular Physics, 103(21-23):2873-2895, 2005 (article)

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[BibTex]

[BibTex]


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Reversible diffusion-limited reactions: "Chemical Equilibrium" state and the Law of Mass Action revisited

Voituriez, R., Moreau, M., Oshanin, G.

Europhysics Letters, 69(2):177-183, 2005 (article)

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[BibTex]

[BibTex]


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The depletion potential in one, two and three dimensions

Roth, R., König, P. M.

Pramana - Journal of Physics, 64(6):971-980, 2005 (article)

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[BibTex]

[BibTex]


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Interplay between geometry and fluid properties

König, P.-M.

Universität Stuttgart, Stuttgart, 2005 (phdthesis)

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link (url) [BibTex]

link (url) [BibTex]


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Saltatory drift in a randomly driven two-wave potential

Oshanin, G., Klafter, J., Urbakh, M.

Journal of Physics: Condensed Matter, 17(47, Sp. Iss. SI):S3697-S3707, 2005 (article)

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[BibTex]

[BibTex]


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A thin-film equation for viscoelastic liquids of Jeffreys type

Rauscher, M., Münch, A., Wagner, B., Blossey, R.

European Physical Journal E, 17(3):373-379, 2005 (article)

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[BibTex]

[BibTex]


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Curvature expansion of density profiles

König, P.-M., Bryk, P., Mecke, K. R., Roth, R.

Europhysics Letters, 69(5):832-838, 2005 (article)

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[BibTex]

[BibTex]


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General methods for free-volume theory

Oversteegen, S. M., Roth, R.

Journal of Chemical Physics, 122(21), 2005 (article)

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[BibTex]

[BibTex]


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Morphological characterisation of point patterns

Mecke, K., Stoyan, D.

Biometrical Journal, 47, pages: 1-16, 2005 (article)

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[BibTex]

[BibTex]


Negative refraction at optical frequencies in nonmagnetic two-component molecular media
Negative refraction at optical frequencies in nonmagnetic two-component molecular media

Chen, Y., Fischer, P., Wise, F.

PHYSICAL REVIEW LETTERS, 95(6), 2005 (article)

Abstract
There is significant motivation to develop media with negative refractive indices at optical frequencies, but efforts in this direction are hampered by the weakness of the magnetic response at such frequencies. We show theoretically that a nonmagnetic medium with two atomic or molecular constituents can exhibit a negative refractive index. A negative index is possible even when the real parts of both the permittivity and permeability are positive. This surprising result provides a route to isotropic negative-index media at optical frequencies.

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DOI [BibTex]

DOI [BibTex]


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Thermodynamic Casimir force in models of 4He films

Dantchev, D., Krech, M., Dietrich, S.

Physical Review Letters, 95(25), 2005 (article)

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[BibTex]

[BibTex]


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Capillary-induced interactions between colloids at an interface

Dominguez, A., Oettel, M., Dietrich, S.

Journal of Physics: Condensed Matter, 17(45):S3387-S3392, 2005 (article)

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[BibTex]

[BibTex]


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Homogeneous and inhomogeneous hard-sphere mixtures: manifestations of structural crossover

Grodon, C., Dijkstra, M., Evans, R., Roth, R.

Molecular Physics, 103, pages: 3009-3023, 2005 (article)

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[BibTex]

[BibTex]